119294-64-3

Basic information

• Product Name: N-[4-Methyl-5-(5-nitro-furan-2-yl)-thiazol-2-yl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazine
• CAS NO: 119294-64-3
• Molecular Weight: 328.351
• Mol File: 119294-64-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[4-Methyl-5-(5-nitro-furan-2-yl)-thiazol-2-yl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[4-Methyl-5-(5-nitro-furan-2-yl)-thiazol-2-yl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazine(119294-64-3)
• EPA Substance Registry System: N-[4-Methyl-5-(5-nitro-furan-2-yl)-thiazol-2-yl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazine(119294-64-3)

Safety Data

• Hazardous Substances Data: 119294-64-3(Hazardous Substances Data)

Upstream product

• 1627-73-2 1-benzylidene thiosemicarbazide 
• 20782-91-6 2-(bromomethyl)-5-nitrofuran 
• 119321-45-8 4-acetyl-1-benzylidene-3-(5-nitro-2-furfuryl)thiosemicarbazide 
• 119321-40-3 1-benzylidene-3-(5-nitro-2-furfuryl)thiosemicarbazonium bromide 

Relevant articles and documents

4-Acetyl-1-(R-benzylidene)-3-(5-nitro-2-furfuryl)thiosemicarbazides - Carriers of Synthones for Obtaining Thiazole and Triazole Rings

The corresponding thiosemicarbazonium salts, which form 4-acetyl- and 2,4-diacetyl-1-benzylidene-3-(5-nitro-2-furfuryl)thiosemicarbazides with acetic anhydride, were obtained by the reaction of 5-nitrofurfuryl bromide with 1-benzylidenethiosemicarbazides.Under the influence of bases the monoacetylated derivatives undergo cyclization to the corresponding 2-benzylidenehydrazino-5-(5-nitro-2-furyl)thiazoles.Intramolecular cyclization of the monoacetylated products to 3-methyl-5--1,2,4-triazole, which is accompanied by the elimination of the corresponding benzaldehyde, occurs in the presence of hydrochloric acid.