119305-76-9Relevant academic research and scientific papers
Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation
Zhang, Junlin,Wang, Leming,Liu, Qi,Yang, Zhen,Huang, Yong
supporting information, p. 11662 - 11664 (2013/12/04)
α,β-Unsaturated ketones and aldehydes have been synthesized from their corresponding silyl enol ethers in a straightforward protocol involving a visible-light promoted organocatalytic, aerobic oxidation reaction. A cheap organic dye was used catalytically in these reactions as the photosensitizer.
REGIO- AND STEREOSELECTIVE PREPARATION OF SILYL ENOL ETHERS BY ALKYLIDENATION OF SILYL ESTERS
Takai, Kazuhiko,Kataoka, Yasutaka,Okazoe, Takashi,Utimoto, Kiitiro
, p. 1065 - 1068 (2007/10/02)
Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
