119322-57-5

Upstream product

• 78136-24-0 1,2:4,5-bis-O-(1-methylethylidene)-3,3'-anhydro-3-C-(hydroxymethyl)-β-D-fructopyranose 
• 119155-88-3 C₁₆H₂₉BrO₆Si 
• 119155-87-2 C₁₃H₂₀O₅ 
• 119155-89-4 (3S,4R,5R)-3-Bromomethyl-2,5-bis-hydroxymethyl-2-methoxy-tetrahydro-furan-3,4-diol 
• 69351-19-5 Shi's ketone 
• 119206-38-1 C₃₂H₃₃BrO₁₂P₂ 

Relevant academic research and scientific papers

SYNTHESIS OF PHOSPHATE AND PHOSPHATES ISOSTERES OF FURANOSE SUGARS AS POTENTIAL ENZYME INHIBITORS

Various D-furanose monosaccharides were synthesized as possible inhibitors of the gluconeogenic enzyme fructose 1,6-bisphosphatase.These included sulfamate, phosphoramidate, and epoxy analogues of the natural substrate, fructose 1,6-diphosphate (1), and arabinose and ribose analogues of a natural inhibitor, fructose 2,6-diphosphate (2).NMR studies were conducted to establish the stereochemistry of phosphate displacement at Cl in the synthesis of arabinose 1-phosphate derivatives. β-Ribose 1,5-diphosphate (35b) was prepared with >95 percent stereoselectivity.