119327-33-2

Basic information

• Product Name: (Z)-trimethyl<2-(2-carbomethoxyphenyl)ethenyl>silane
• CAS NO: 119327-33-2
• Molecular Weight: 234.37
• Mol File: 119327-33-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-trimethyl<2-(2-carbomethoxyphenyl)ethenyl>silane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-trimethyl<2-(2-carbomethoxyphenyl)ethenyl>silane(119327-33-2)
• EPA Substance Registry System: (Z)-trimethyl<2-(2-carbomethoxyphenyl)ethenyl>silane(119327-33-2)

Safety Data

• Hazardous Substances Data: 119327-33-2(Hazardous Substances Data)

Upstream product

• 610-97-9 o-iodo-methyl-benzoic acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 18178-59-1 (E)-1,2-bis(trimethylsilyl)ethene 

Relevant articles and documents

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

The direct olefination of aryl/alkyl halides with trimethylsilyldiazomethane (TMSD) as a C1- or C2-unit was achieved successfully via a metal carbene migratory insertion process, which offered a new access to afford (E)-vinyl silanes and (E)-silyl-substituted α,β-unsaturated amides in good yields and high chemoselectivity.