119333-79-8

Upstream product

• 119333-84-5 (Z)-4-methyl-3-<2-(phenylseleno)-1-ethanyl>-4-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one 
• 137200-42-1 3-ethoxy-6-methyl-6-<4-(trimethylsilyl)-2-butynyl>-2-cyclohexen-1-one 
• 111097-70-2 (4-Iodo-but-2-ynyl)-trimethyl-silane 
• 62952-33-4 3-ethoxy-6-methylcyclohex-2-en-1-one 
• 61484-16-0 3-Ethoxy-6-methyl-6-prop-2-ynyl-cyclohex-2-enone 
• 917-57-7 vinyllithium 
• 137200-43-2 (Z)-3-ethoxy-6-methyl-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one 

Downstream Products

• 119333-84-5 (Z)-4-methyl-3-<2-(phenylseleno)-1-ethanyl>-4-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Cyclooctane or Cyclohexane Annulations Based on Intramolecular Additions of Allylsilanes to Conjugated Dienones

The scope and limitations of alkenyl dienone cyclizations for the formation of fused cyclooctane or cyclohexane systems are described.

A NEW APPROACH FOR THE FORMATION OF FUSED CYCLOOCTANE OR CYCLOHEXANE RINGS

The intramolecular regioselective addition of unsymmetrical allylsilanes to conjugated dienones is shown to permit facile entry into 5-6, 6-6, 5-8, and 6-8 bicyclic ring systems.