119342-37-9Relevant academic research and scientific papers
Synthesis and Properties of Indolo-3,3'-Trimethinecyanines Substituted in the Polymethine Chain and Heterorings
Karymova, T. M.,Abramenko, P. I.,Kurkina, L. G.
, p. 736 - 740 (1988)
New 8-chloro-, 9-cyano-, and 8-methyl-9-carboxy-substituted (in the outer polymethine chain), indolo-3,3'-trimethinecyanines containing substituents in the 2, 5, or 7 positions of the indole heteroresidues were synthesized, and their spectral, polarographic, and photographic properties were studied.It is shown that electron-acceptor substituents in the 2 and 2' positions of the indole heteroresidues and the 8 and/or 9 positions of the polymethine chain of the dye molecules that do not have steric hindrance give rise to a bathochromic shift of their absorption maxima. 8-Chloro-, 9-cyano- and 8-methyl-9-carbethoxyindolo-3,3'-trimethinecyanines with electron-acceptor groups in the 2 and 2' positions are ineffective sensitizers of direct positive silver halide emulsions.
