1193641-53-0

Basic information

• Product Name: 6-fluoro-1,2,3,4-tetraphenylnaphthalene
• Synonyms: 6-fluoro-1,2,3,4-tetraphenylnaphthalene
• CAS NO: 1193641-53-0
• Molecular Weight: 450.555
• Mol File: 1193641-53-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 6-fluoro-1,2,3,4-tetraphenylnaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 6-fluoro-1,2,3,4-tetraphenylnaphthalene(1193641-53-0)
• EPA Substance Registry System: 6-fluoro-1,2,3,4-tetraphenylnaphthalene(1193641-53-0)

Safety Data

• Hazardous Substances Data: 1193641-53-0(Hazardous Substances Data)

Upstream product

• 427-39-4 (4-fluorophenyl)diphenylmethanol 
• 501-65-5 diphenyl acetylene 
• 456-22-4 4-Fluorobenzoic acid 
• 445-29-4 o-fluoro-benzoic acid 
• 455-38-9 3-fluorobenzoic acid 
• 1073-06-9 3-fluorobromobenzene 
• 768-35-4 3-fluorophenylboronic acid 
• 1765-93-1 4-fluoroboronic acid 

Relevant articles and documents

Synthesis of Benzo-Fused Cyclic Compounds via Rhodium-Catalyzed Decarboxylative Coupling of Aromatic Carboxylic Acids with Alkynes

The decarboxylative coupling of diversely substituted benzoic acids with internal alkynes proceeds smoothly in the presence of a [RhCl(cod)] 2/1,2,3,4-tetraphenyl-1,3-cyclopentadiene catalyst system to selectively produce highly substituted nap

Room Temperature Decarboxylative and Oxidative [2+2+2] Annulation of Benzoic Acids with Alkynes Catalyzed by an Electron-Deficient Rhodium(III) Complex

It has been established that an electron-deficient (η5-cyclopentadienyl)rhodium(III) [CpERhIII] complex is capable of catalyzing the decarboxylative and oxidative [2+2+2] annulation of benzoic acids with alkynes to produce substituted naphthalenes at room temperature. The appropriate choice of the additive and the solvent is crucial for this transformation. This catalyst system allowed use of oxygen as a terminal oxidant and broadened the substrate scope including both aromatic and aliphatic alkynes. In this catalysis, the electron deficient nature of the CpERhIII catalyst would cause the strong rhodium-π interaction, which accelerates the decarboxylation as well as the C?H bond cleavage.

Solvent free, phosphine free Pd-catalyzed annulations of aryl bromides with diarylacetylenes

Palladium nanoparticles and sodium acetate catalyze the reaction of aryl bromide with diarylacetylene to produce annulated products in good yield. One equivalent of PEG-600 serves as the solvent. This procedure is compatible with a wide variety of functional groups.