119403-37-1Relevant academic research and scientific papers
α,α-DISUBSTITUTED POLYFLUOROALKANES
Zapevalov, A. Yu.,Saloutina, L. V.,Kodess, M. I.,Kolenko, I. P.
, p. 1466 - 1472 (2007/10/02)
The reaction of 1,1,ω-trihydropolyfluoro-1-alkanols with triphenyldichloro- and triphenyldibromophosphorus gave 1-chloro- and 1-bromo-1,1,ω-trihydropolyfluoroalkanes.The 1,2-elimination of HF from the alkanes by the action of basic agents led to the formation of 1-chloro(bromo)-1,ω-dihydropolyfluoro-1-alkenes in the E form. 1,2-Dehalogenation (1-Br, 2-F) of the 1-bromo-1,1,ω-trihydropolyfluoroalkanes by the action of zinc made it possible to obtain the 1,1,ω-trihydropolyfluoro-1-alkenes. 1,2-Dehalogenation (1-Cl, 2-F) of the 1-chloro-1,1,ω-trihydropolyfluoroalkanes does not take place under analogous conditions.
