119405-89-9

Basic information

• Product Name: (Z)-oct-3-en-1-ylbenzene
• Synonyms: (Z)-oct-3-en-1-ylbenzene
• CAS NO: 119405-89-9
• Molecular Weight: 188.313
• Mol File: 119405-89-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (Z)-oct-3-en-1-ylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-oct-3-en-1-ylbenzene(119405-89-9)
• EPA Substance Registry System: (Z)-oct-3-en-1-ylbenzene(119405-89-9)

Safety Data

• Hazardous Substances Data: 119405-89-9(Hazardous Substances Data)

Upstream product

• 127411-81-8 C₄H₉Cl₂La 
• 497107-80-9 (E)-4-phenyl-1-trimethylsilyl-1,2-epoxybutane 
• 94616-73-6 n-butylcerium dichloride 
• 1126-76-7 1,2-Epoxy-4-phenylbutane 
• 100347-31-7 C₁₆H₃₆Ce^(1-)*Li⁽¹⁺⁾ 
• 104-53-0 3-phenyl-propionaldehyde 
• 693-02-7 hex-1-yne 
• 109-72-8 n-butyllithium 
• 127411-77-2 Dimethyl-(3-phenethyl-oxiranyl)-phenyl-silane 
• 21406-61-1 pentyltriphenylphosphonium bromide 
• 768-56-9 4-Phenylbut-1-ene 

Relevant articles and documents

Copper-catalyzed reduction of alkyl triflates and iodides: An efficient method for the deoxygenation of primary and secondary alcohols

We describe an effective method for catalytic reduction of 1°alkyl sulfonates, and 1°and 2°iodides in the presence of a wide range of functional groups. This Cu-catalyzed reaction provides a means for the effective deoxygenation of alcohols, as demonstrated by the highly selective reduction of 1°alcohols using a triflation/reduction sequence. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Primarily reduced: The copper-catalyzed reduction of 1°alkyl sulfonates, and 1°and 2°iodides, which is effective in the presence of a wide range of functional groups, provides a means for the effective deoxygenation of alcohols. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Copyright

Ru-catalyzed decarbonylative addition of aliphatic aldehydes to terminal alkynes

(Figure Presented) A novel method for the formation of isolated C - C bonds was developed via a ruthenium-catalyzed decarbonylative addition of aliphatic aldehydes and alkynes. An unprecedented complete switch of chemoselectivity from aromatic aldehydes to aliphatic aldehydes was observed simpl y by using tri(2,4,6-trismethoxyphenyl)phosphine as ligand. A synthesis by this method of an insect sex pheromone was demonstrated.

DIRECT PREPARATION OF SUBSTITUTED OLEFINS FROM EPOXIDES UTILIZING LITHIUM TETRAALKYLCERATE

Alkylated olefins were directly synthesized in good yields by the deoxygenation reaction of epoxides with concomitant introduction of the alkyl group using lithium tetraalkylcerate.Styreneoxide and (1-naphtyl)ethyleneoxide gave terminal olefins, while ethyleneoxide replaced by alphatic substituent, 1,2-epoxy-4-phenylbutane, afforded internal olefin.The utility of the present method was demonstrated in the one-step synthesis of a sesquiterpene, dehydro-α-curcumene.