119406-10-9Relevant academic research and scientific papers
A Route to Vicinal Diamines from the Samarium(II) Iodide-Mediated Coupling of Aldimines
Enholm, Eric J.,Forbes, David C.,Holub, David P.
, p. 981 - 987 (2007/10/02)
A new method to construct vicinal diamines from aldimines mediated by the one electron reductant, samarium diiodide is described.The reaction probably involves a ketyl-like radical coupling mechanism.
REDUCTIVE DIMERIZATION OF IMINES IN A Pb/Al BIMETAL REDOX SYSTEM
Tanaka, Hideo,Dhimane, Hamid,Fujita, Hiroyuki,Ikemoto, Youichi
, p. 3811 - 3814 (2007/10/02)
Reductive dimerization of N-alkylimines into vicinal diamines has been performed by the action of a catalytic amount of lead(II) bromide and aluminum (1 equiv.) in THF containing trifluoroacetic acid (TFA) or aluminum(III) bromide.
