1194063-80-3Relevant academic research and scientific papers
Configuration-dependent ring opening of silyloxiranes: synthesis of functionalized alkenes or tetrahydrofurans
Lange, Jens,Schaumann, Ernst
, p. 4674 - 4684 (2009)
cis- and trans-Silyloxiranes with a potential tosylate or bromide leaving group in the β position are available by the diastereospecific reduction of the corresponding alkynes with DIBAL-H and hydrosilylation with silanes, respectively. In the reaction wi
