119435-10-8Relevant academic research and scientific papers
A simple asymmetric organocatalytic approach to optically active cyclohexenones
Carlone, Armando,Marigo, Mauro,North, Chris,Landa, Aitor,Jorgensen, Karl Anker
, p. 4928 - 4930 (2007/10/03)
Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of β-ketoesters to α,β-unsaturated aldehydes that proceeds in aque
Simple and practical routes to enantiomerically pure 5-(Trialkylsilyl)-2-cyclohexenones
Sarakinos, Georgios,Corey
, p. 811 - 814 (2008/02/12)
Formula presented Enantiomerically pure chiral 5-silylated 2-cyclohexenones are easily prepared in high yield using as a key step kinetic resolution with a commercially available lipase. Fully active enzyme can be recovered very efficiently for reuse. The
Synthesis of (R)-(+)-4-Butyl-2,6-cycloheptadienone, a Constituent of Marine Algae
Asaoka, Morio,Takenouchi, Kazuya,Takei, Hisashi
, p. 921 - 922 (2007/10/02)
The title compound was synthesized from (R)-(-)-5-trimethylsilyl-2-cyclohexenone in 19percent overall yield.
