119439-19-9Relevant academic research and scientific papers
Biogenetic-Type Synthesis of (+)-Cymbodiacetal, a Constituent of Cymbopogon martinii
D'Souza, Asha M.,Paknikar, Shashikumar K.,Dev, Vasu,Beauchamp, Philip S.,Kamat, Shrivallabh P.
, p. 700 - 702 (2004)
A biogenetic-type synthesis of (+)-cymbodiacetal (1), a novel bismonoterpenoid dihemiacetal, is described.
Progress toward the Enantioselective Synthesis of Curcusones A-D via a Divinylcyclopropane Rearrangement Strategy
Wright, Austin C.,Lee, Chung Whan,Stoltz, Brian M.
, p. 9658 - 9662 (2019/12/02)
We report our iterative efforts toward the divergent total syntheses of curcusones A-D via Suzuki coupling, intramolecular cyclopropanation, and a key divinylcyclopropane rearrangement. Progress of our synthesis was repeatedly challenged by the highly sub
Total synthesis of (+)-cymbodiacetal: A re-evaluation of the biomimetic route
Uroos, Maliha,Lewis, William,Blake, Alexander J.,Hayes, Christopher J.
experimental part, p. 8465 - 8470 (2011/04/15)
A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-selectivity (2:1, endo/exo) in quantitative yield, and t
