119447-87-9

Upstream product

• 120818-50-0 (4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-[(3S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yloxy]-tetrahydro-pyran-2-carboxylic acid 
• 17608-41-2 cholestanol 
• 129885-86-5 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate 
• 120818-49-7 methyl <3β-cholestanyl 4,5,7-tri-O-benzyl-2-deoxy-αβ-D-arabino-2-heptulopyranosid>onate 
• 119005-63-9 methyl onate 
• 119447-82-4 (2R,3R,4S,5R,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yloxy]-5-phenylsulfanyl-tetrahydro-pyran 
• 80-97-7 Cholestanol 
• 160549-11-1 3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranose 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 117901-42-5 3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranose 
• 119447-81-3 O-(3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranosyl)trichloroacetimidate 

Relevant academic research and scientific papers

An efficient method for catalytic and stereoselective synthesis of 2-deoxy-α-D-glucopyranosides from 3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranose and several alcoholic nucleophiles

Several 2-deoxy-α-D-glucopyranosides are stereoselectively synthesized in high yields by glycosylation of various alcoholic nucleophiles with 3,4,6-tri-O-benzyl-2-deoxy-glucopyranose using a catalytic amount of trityl tetrakis(pentafluorophenyl) borate.

Diastereoselective Free-radical Reactions. Part 1. Preparation of 2-Deoxy-β-glycosides by Synthesis and Reductive Decarboxylation of 3-Deoxyulosonic Acid Glycosides

A general procedure for the synthesis of 2-deoxy-β-D-glycosides involving the preparation of 3-deoxyulosonic acid glycosides from glycals and their reductive decarboxylation is described.

A Convenient 2-Deoxy-α-D-glucopyranosylation Reaction Using Dimethylphosphinothioate Method

Several 2-deoxy-α-glucosides were obtained in good yields with high stereoselectivity by glycosylation reaction of the corresponding alcohols with 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate in the presence of a catalytic amount of triphenylmethylium perchlorate or an equivalent amount of silver perchlorate.

A Convenient Synthesis of 2-Deoxy-β-D-glucopyranosides

The O-(2-deoxy-2-phenylthio-α-D-glucopyranosyl) trichloroacetimidate α-3 was obtained from 3,4,6-tri-O-benzyl-D-glucal (1) in a two-step procedure.This compound is a powerful glucopyranosyl donor, which with typical alcohol acceptors provided mainly the c