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119450-05-4

(2RS,3SR)-2,3-dibromo-3-o-tolyl-propionic acid is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 119450-05-4 Structure

  • Basic information

    1. Product Name: (2RS,3SR)-2,3-dibromo-3-o-tolyl-propionic acid
    2. Synonyms:
    3. CAS NO:119450-05-4
    4. Molecular Formula:
    5. Molecular Weight: 321.996
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 119450-05-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (2RS,3SR)-2,3-dibromo-3-o-tolyl-propionic acid(CAS DataBase Reference)
    10. NIST Chemistry Reference: (2RS,3SR)-2,3-dibromo-3-o-tolyl-propionic acid(119450-05-4)
    11. EPA Substance Registry System: (2RS,3SR)-2,3-dibromo-3-o-tolyl-propionic acid(119450-05-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 119450-05-4(Hazardous Substances Data)

119450-05-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 119450-05-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,9,4,5 and 0 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 119450-05:
(8*1)+(7*1)+(6*9)+(5*4)+(4*5)+(3*0)+(2*0)+(1*5)=114
114 % 10 = 4
So 119450-05-4 is a valid CAS Registry Number.

119450-05-4Relevant articles and documents

A mild procedure for the stereospecific transformation of trans cinnamic acid derivatives to cis β-bromostyrenes

Kim, Sun Hee,Wei, Han-Xun,Willis, Steven,Li, Guigen

, p. 4179 - 4185 (1999)

A new mild procedure has been developed for the synthesis of cis β- bromostyrene analogs with complete Z/E selectivity and good to excellent yields (58.4 - 90.9 %). The process involves carboxyl-halo-elimination of cinnamic acid dibromides by using triethylamine in N,N-dimethylformamide at room temperature. A one-pot procedure has also been described for the direct transformation of cinnamic acids to β-bromostyrenes.

Iodide-induced Debromination of Cinnamic Acid and Substituted Cinnamic Acid Dibromides in 2-Methoxyethanol

Subramanian, K.,Mathai, I. M.

, p. 909 - 911 (2007/10/02)

The second order rate constants for the iodide-induced debromination of cinnamic acid and substituted cinnamic acid dibromides in 2-methoxyethanol are reported; the reactivities follow the order: p-OCH3 > o-CH3 > p-CH3 > p-NO2 > p-Cl > m-NO2 > -H > m-CH3 > m-OCH3 > o-Cl.The m-CH3 and p-Cl derivatives have higher enthalpies and lower negative entropies of activation whereas methoxy substituted derivatives are characterised by lower enthalpies and higher negative entropies of activation than the unsubstituted acid.The free energy of activation is nearly constant.

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