119457-70-4

Basic information

• Product Name: 2,6-diphenyl-1,1,3,3,4,4,5,5,7,7-decafluoro-1,6-heptadiene
• CAS NO: 119457-70-4
• Molecular Weight: 428.272
• Mol File: 119457-70-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,6-diphenyl-1,1,3,3,4,4,5,5,7,7-decafluoro-1,6-heptadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-diphenyl-1,1,3,3,4,4,5,5,7,7-decafluoro-1,6-heptadiene(119457-70-4)
• EPA Substance Registry System: 2,6-diphenyl-1,1,3,3,4,4,5,5,7,7-decafluoro-1,6-heptadiene(119457-70-4)

Safety Data

• Hazardous Substances Data: 119457-70-4(Hazardous Substances Data)

Upstream product

• 75-61-6 dibromodifluoromethane 
• 2525-83-9 2,2,3,3,4,4-hexafluoro-1,5-diphenylpentane-1,5-dione 

Downstream Products

• 119457-74-8 2,6-diphenyl-1,1,1,3,4,4,5,7,7,7-decafluoro-(Z,Z)-2,5-heptadiene 

Relevant articles and documents

SYNTHESIS AND ISOMERIZATION OF 2,5- AND 2,6-SUBSTITUTED F-HEXADIENES AND HEPTADIENES

The reaction of 2,2,3,3,4,4-hexafluoro-1,5-diphenylpentane-1,5-dione, 4,4,5,5-tetrafluorooctane-3,6-dione and 4,4,5,5,6,6-hexafluorononane-3,7-dione with excess triphenylphosphine and dibromodifluoromethane in triglyme at 70 deg C gave modest yields (50-60 percent) of the corresponding dienes and enones (10-20 percent).No isomerized olefins were observed.Subsequent treatment of the dienes with tetraethylammonium fluoride gave the internal olefins, and thermal isomerization of 2,6-diphenyl-1,1,3,3,4,4,5,5,7,7-decafluoro-1,6-heptadiene to the internal isomeric olefins was observed at 250 deg C.