119458-72-9Relevant academic research and scientific papers
Synthesis of 4H-Benzopyranothiadiazol-4-one and Its Reactions with Some Nucleophilic and Electrophilic Agents
Savel'ev, V. L.,Samsonova, O. L.,Troitskaya, V. S.,Vinokurov, V. G.,Lezina, V. P.,Smirnov, L. D.
, p. 805 - 810 (2007/10/02)
The reaction of 3,4-diaminocoumarin with thionyl chloride gave 4H-benzopyranothiodiazol-4-one (II), which was cleaved by the action of nucleophilic agents to the corresponding 4-(2-hydroxyphenyl)-1,2,5-thiadiazole-3-carboxylic acid derivatives.The nitration of II leads to the 8-nitro or 6,8-dinitro derivative; the latter was isolated in the form of 4-(2-hydroxy-3,5-dinitrophenyl)-1,2,5-thiadiazole-3-carboxylic acid.
