1194630-48-2Relevant academic research and scientific papers
Addition of kinetic boron enolates generated from β-alkoxy methyl ketones to aldehydes. Density functional theory calculations on the transition structures
Dias, Luiz C.,Pinheiro, Sávio M.,de Oliveira, Vanda M.,Ferreira, Marco A.B.,Tormena, Cláudio F.,Aguilar, Andrea M.,Zukerman-Schpector, Julio,Tiekink, Edward R.T.
supporting information; experimental part, p. 8714 - 8721 (2009/12/26)
Herein we report that good to excellent levels of 1,5-anti stereoinduction are obtained in boron enolate aldol reactions of 1,2-syn β-alkoxy methyl ketones with achiral aldehydes, when the β-alkoxy protecting group is part of a benzylidene acetal. We have
