119472-80-9Relevant academic research and scientific papers
Consequences of modulated precompression along reaction coordinates. Synthesis, crystallographic structural studies, and rate of intramolecular dyotropy in an extended series of syn-sesquinorbornene disulfones
O'Doherty, George A.,Rogers, Robin D.,Paquette, Leo A.
, p. 10883 - 10894 (2007/10/02)
In order to produce a broad range of syn-sesquinorbornene disulfones, (Z)-1,2-bis(phenylsulfonyl)ethylene was added in Diels - Alder fashion (high-pressure conditions) to tricyclo[5.2.1.02,6]deca-2,5,8-trienes carrying isopropylidene or spirocy
Protocol for Multiple Functionalization of the Peristylane Perimeter. Density Relationships between the 2,4,6-Trione, 2,4,6,8-Tetrone, and Related Isopropylidene Congeners
Paquette, Leo A.,Shen, Chien-Chang,Engel, Peter
, p. 3329 - 3333 (2007/10/02)
Details are provided for the synthesis of the tri- and tetraketones in the peristylane series.Access to the latter of these compounds represents arrival at that derivative in which all four available methylene carbons are oxidized.Two approaches to 1 h
EXTENDED FUNCTIONALIZATION OF THE FLUTED PERISTYLANE PERIMETER
Paquette, Leo A.,Shen, Chien-Chang
, p. 4069 - 4072 (2007/10/02)
Syntheses of peristylane-2,4,6-trione (11) and 2,4,6,8-teraone (17) are described.In 17, all four of the methylene carbons present in the parent pristylane ring system are seen to be oxidized.The C4v symmetry of the tetraketone is reflect
