119477-58-6Relevant academic research and scientific papers
Use of zinc enolate, free from other metals, in enantioselective palladium-catalyzed allylic alkylation
Kinoshita, Naosumi,Kawabata, Takeo,Tsubaki, Kazunori,Bando, Masahiko,Fuji, Kaoru
, p. 1756 - 1763 (2007/10/03)
Zinc enolate, free from other metal cations directly prepared from malonate and diethylzinc, was proven to be an excellent nucleophile for enantioselective palladium-catalyzed allylic alkylation, particularly for the allylic cation bearing aromatic rings
MODIFICATION OF OPTICALLY ACTIVE FERROCENYLPHOSPHINE LIGANDS FOR PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC ALKYLATION
Hayashi, Tamio,Yamamoto, Akihiro,Hagihara, Toshiya,Ito, Yoshihiko
, p. 191 - 194 (2007/10/02)
Optically active ferrocenylphosphines containing a functional group on the side chain were effective as ligands for the palladium-catalyzed asymmetric allylic alkylation of 1,3-disubstituted allyl acetates such as 1,3-diphenyl-3-acetoxy-1-propene with sod
