119477-63-3Relevant academic research and scientific papers
Asymmetric Allylic Alkylation of 1,3-Disubstituted 2-Propenyl Acetetes Catalyzed by a Chiral Ferrocenylphosphine-Palladium Complex
Hayashi, Tamio,Yamamoto, Akihiro,Ito, Yoshihiko
, p. 177 - 180 (2007/10/02)
Reaction of racemic 2-propenyl acetates substituted with two different aryl groups at 1 and 3 positions with sodium acetylacetonate in the presence of a palladium catalyst containing an optically active ferrophosphine ligand gave regioisomeric allylic alkylation products of high optical purity (up to 95 percent ee).
