119480-95-4Relevant academic research and scientific papers
An efficient procedure for the preparation of chiral β-substituted (E)-crotylsilanes: Application of a rhodium(II) catalyzed silylformylation of terminal alkynes
Jain,Jain, Nareshkumar F.,Cirillo,Cirillo, Pier F.,Schaus,Schaus, Jennifer V.,Panek,Panek, James S.
, p. 8723 - 8726 (2007/10/02)
Functionalized β-substituted (E)-crotylsilanes (R)-7 and (S)-8, bearing an alkyl or aryl group adjacent to the stereogenic C-Si center have been synthesized in an efficient four-step procedure initiated with a regio- and stereoselective silylformylation o
