119487-86-4

Upstream product

• 119487-82-0 [(1S,2S)-2-Chloro-1-phenyl-2-(toluene-4-sulfinyl)-propyl]-phenyl-amine 
• 50635-71-7 1-chloroethyl p-tolyl sulfoxide 
• 538-51-2 benzylidene phenylamine 
• 119487-82-0 [(1S,2S)-2-Chloro-1-phenyl-2-((S)-toluene-4-sulfinyl)-propyl]-phenyl-amine 
• 122406-39-7 [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-propyl]-phenyl-amine 
• 31350-93-3 (-)-(R)-1-chloroethyl p-tolyl sulfoxide 

Downstream Products

• 3683-70-3 2-methyl-1,3-diphenylaziridine 
• 122333-55-5 C₈H₉⁽²⁾HOS 
• 6378-07-0 ethyl (p-tolyl)sulfoxide 
• 122356-70-1 2-deuterio-2-methyl-1,3-diphenylaziridine 
• 122406-41-1 (-)-(2R,3S)-1,2-diphenyl-3-methylaziridine 
• 122333-57-7 N-((E)-1-Methyl-2-phenyl-vinyl)-N-phenyl-acetamide 
• 122333-56-6 1-(2-Methyl-1,3-diphenyl-aziridin-2-yl)-ethanol 

Relevant academic research and scientific papers

Generation of Aziridinyllithiums from Sulfinylaziridines by the Ligand Exchange Reaction of Sulfoxides with tert-Butyllithium: Their Properties and An Application to Asymmetric Synthesis of α-Dialkylamino Acid Ester

Aziridinyllithiums were generated from sulfinylaziridines by the ligand exchange reaction of sulfoxides with tert-butyllithium.The aziridinyllithiums were found to be stable in THF at below -30 deg C and reactive with several electrophiles such as carbony

Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz

STEREOSPECIFIC DESULFINYLATION OF SULFINYLAZIRIDINES WITH ETHYLMAGNESIUM BROMIDE: A NOVEL SYNTHESIS OF (Z)-N-ARYLAZIRIDINES

A novel synthesis of (Z)-N-arylaziridines was realised by the stereospecific desulfinylation of (E)-(N-aryl)sulfinylaziridines which were synthesized from 1-chloroalkyl p-tolyl sulfoxides and N-arylimines in high yields.