119490-06-1Relevant academic research and scientific papers
Optically active α-phenylethylamine as efficient organocatalyst in the solvent-free reactions between 2,3-butanedione and conjugated nitroolefins
Felluga, Fulvia,Forzato, Cristina,Nitti, Patrizia,Pitacco, Giuliana,Prati, Fabio,Valentin, Ennio,Zangrando, Ennio
, p. 1005 - 1012 (2013/03/14)
(R)-(+) and (S)-(-)-1-phenylethylamine have been shown to promote highly diastereoselective and complementary enantioselective formal [3 + 2]carbocyclization reactions between 2,3-butanedione and conjugated nitroalkenes with formation of enantiomerically
Diastereo- and Enantio-selective Cyclopentaannulations from Diacetyl Monoimines and Nitroalkenes.
Felluga, Fulvia,Nitti, Patrizia,Pitacco, Guliana,Valentin, Ennio
, p. 709 - 734 (2007/10/02)
The acyclic α-ketoenamines (1) and (2) derived from butane-2,3-dione were allowed to react with a series of conjugated nitroalkenes, both linear and cyclic in nature.The reactions afforded polysubstituted cyclopentanone imines which were hydrolyzed to the
A FACILE ROUTE TO POLYSUBSTITUTED 2-HYDROXY-3-NITRO-CYCLOPENTANONES VIA A LINEAR α-KETOENAMINE
Felluga, F.,Nitti, P.,Pitacco, G.,Valentin, E.
, p. 4165 - 4168 (2007/10/02)
The morpholino monoenamine of diacetyl has been synthesized and reacted with conjugated nitroolefins to give functionalized cyclopentanone derivatives, after hydrolysis of the isolated enamine intermediates.
