119548-69-5

Basic information

• Product Name: N-methyl-N-(2,4-dinitrophenyl)glycine methyl ester
• Synonyms: N-methyl-N-(2,4-dinitrophenyl)glycine methyl ester
• CAS NO: 119548-69-5
• Molecular Weight: 269.214
• Mol File: 119548-69-5.mol

Chemical Properties

• CAS DataBase Reference: N-methyl-N-(2,4-dinitrophenyl)glycine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-(2,4-dinitrophenyl)glycine methyl ester(119548-69-5)
• EPA Substance Registry System: N-methyl-N-(2,4-dinitrophenyl)glycine methyl ester(119548-69-5)

Safety Data

• Hazardous Substances Data: 119548-69-5(Hazardous Substances Data)

Upstream product

• 13515-93-0 N-methylglycine methyl ester hydrochloride 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 5473-12-1 N-methylglycine methylester 

Downstream Products

• 116059-14-4 1-hydroxy-4-methyl-7-nitroquinoxaline-2,3-dione 
• 116059-13-3 2-amino-2'-methylamino-5,5'-dinitro-ONN-azoxybenzene 
• 89792-22-3 2-nitroso-4-nitro-N-methylaniline 

Relevant articles and documents

o-Nitroaniline derivatives - 13. Reactions of N-(o-nitroaryl)sarcosine esters with bases

The title reactions give 1-hydroxy-4-methylquinoxaline-2,3-diones (4) together with a variety of mono- and bi-cyclic byproducts. All of these may result from a common intermediate, viz. a 1-hydroxy-4-methyl-3,4-dihydro-1H-2,1,4-benzoxadiazine-3-carboxylat

REACTIONS OF METHYL ESTERS OF N-(2,4-DINITROPHENYL)GLYCINE AND N-METHYL-N-(2,4-DINITROPHENYL)GLYCINE WITH SODIUM METHOXIDE

The reaction of methyl ester of N-(2,4-dinitrophenyl)glycine (I) with sodium methoxide produces 5-nitro-2(3H)benzimidazolone (III).The product identity has been proved by its isolation from the reaction mixture under conditions similar to those of kinetic experiments and by independent synthesis.The reaction of methyl ester of N-methyl-N-(2,4-dinitrophenyl)glycine with methoxide proceeds in two steps, the second one being substantially slower.The first step produces N-methyl-2-nitroso-4-nitroaniline (IV), which can be prepared by this reaction in good yield andpurity.N-Methyl-2-nitroso-4-nitroaniline undergoes subsequent reactions in the methoxide solutions.Products of the subsequent reactions have not been identified at the starting ester II concentrations of about 10-4 mol l-1, whereas at higher concentrations of the starting substance the reaction produces 2-amino-2'-methylamino-5,5'-dinitro-ONN-azoxybenzene (V) and 2,2'-bis(methylamino)-5,5'-dinitroazoxybenzene (VI).