1195613-50-3Relevant articles and documents
Mutual induced fit in a synthetic host-guest system
Sawada, Tomohisa,Hisada, Hayato,Fujita, Makoto
supporting information, p. 4449 - 4451 (2014/04/17)
Mutual induced fit is an important phenomenon in biological molecular recognition, but it is still rare in artificial systems. Here we report an artificial host-guest system in which a flexible calix[4]arene is enclathrated in a dynamic self-assembled host and both molecules mutually adopt specific three-dimensional structures. NMR data revealed the conformational changes, and crystallographic studies clearly established the precise structures at each stage.