119564-11-3Relevant academic research and scientific papers
New Transition Metal Complexes with the Ligand Ph2S=N
Roesky, Herbert W.,Zimmer, Michael,Schmidt, Hans Georg,Noltemeyer,Mathias
, p. 1490 - 1494 (2007/10/02)
S,S-Diphenyl-N-(trimethylsilyl)sulfimine (1) reacts in a molar ratio of 1:1 with V(O)Cl3, V(O)F3, NbCl5, MoCl5 and FeCl3 to yield Ph2S=NV(O)Cl2 (2), Ph2S=NV(O)F2 (3), Ph2S=NNbCl4*CH3CN (4), Ph2S=NMoCl4*CH3CN (5) and (Ph2S=NFeCl2)2 (6), respectively.The crystal structures of 2 and (dimeric) 6 are reported. - Keywords: X-Ray, Vanadium, Niobium, Molybdenum, Iron
