1195776-82-9

Basic information

• Product Name: ((methoxymethoxy)methyl-d)benzene
• Synonyms: ((methoxymethoxy)methyl-d)benzene
• CAS NO: 1195776-82-9
• Molecular Weight: 153.185
• Mol File: 1195776-82-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((methoxymethoxy)methyl-d)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((methoxymethoxy)methyl-d)benzene(1195776-82-9)
• EPA Substance Registry System: ((methoxymethoxy)methyl-d)benzene(1195776-82-9)

Safety Data

• Hazardous Substances Data: 1195776-82-9(Hazardous Substances Data)

Upstream product

• 31600-55-2 benzyl methoxymethyl ether 

Relevant articles and documents

Merging α-Lithiation and Aldol-Tishchenko Reaction to Construct Polyols from Benzyl Ethers

α-Lithiobenzyl ethers, generated by selective α-lithiation, undergo an aldol-Tishchenko reaction upon treatment with carboxylic esters and paraformaldehyde. The reaction of the organolithium with the carboxylate generates an intermediate enolate that, after formaldehyde addition, affords 1,2,3-triol derivatives in a straightforward and one-pot manner. These products are obtained as single diastereoisomers bearing a quaternary stereocenter. The complete diastereocontrol of the aldol-Tishchenko process is attributed to stereoelectronic preferences in the transition state.