1195778-26-7

Basic information

• Product Name: C₁₇H₂₂ClNO₃S
• Synonyms: C₁₇H₂₂ClNO₃S
• CAS NO: 1195778-26-7
• Molecular Weight: 355.886
• Mol File: 1195778-26-7.mol

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₂ClNO₃S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₂ClNO₃S(1195778-26-7)
• EPA Substance Registry System: C₁₇H₂₂ClNO₃S(1195778-26-7)

Safety Data

• Hazardous Substances Data: 1195778-26-7(Hazardous Substances Data)

Upstream product

• 63-68-3 L-methionine 
• 1195778-13-2 C₁₀H₁₈NO₂S⁽¹⁺⁾*ClO₄^(1-) 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 1195779-64-6 C₁₈H₂₇ClN₂O₃S 
• 104171-24-6 [(2R,3R)-3-(4-chlorophenyl)oxiran-2-yl]methanol 

Relevant articles and documents

A highly stereoselective synthesis of glycidic amides based on a new class of chiral sulfonium salts: Applications in asymmetric synthesis

A new type of chiral sulfonium salts that are characterized by a bicyclic system has been designed and synthesized from α-amino acids. Their corresponding ylides, which were prepared by basic treatment of the sulfonium salts, reacted smoothly with a broad array of simple and chiral aldehydes to provide trans-epoxy amides in reasonable to very good yields and excellent stereoselectivities (>98 %). The obtained epoxy amides were found to be useful as synthetic building blocks. Thus, they were reduced into their corresponding epoxy alcohols and subjected to oxirane-ring-opening reactions with different types of nucleophiles.

A highly efficient methodology of asymmetric epoxidation based on a novel chiral sulfur ylide

A new type of chiral sulfur ylides has been synthesized and their reactivities against carbonyl compounds tested, showing a high degree of stereoselectivity in the formation of trans epoxy amides under very mild reaction conditions.