119594-52-4Relevant academic research and scientific papers
Regio- and Stereoselectivity in Rearrangements of Bicyclic N,N-Ylides
Fennhoff, Gerhard,Heesing, Albert
, p. 1153 - 1160 (2007/10/02)
Under the influence of strong bases both 2-amino-2-azoniabicyclohept-5-enes and -oct-5-enes rearrange.Insertion of the exocyclic nitrogen products and systems, respectively.Correct stereochemistry at the ammonium atom is necessary for this 2,3-shift. - Keywords: N,N-Ylides; Azabicycles; Rearrangement
