1196084-48-6Relevant articles and documents
Conformational Control of Tetrahydropyran-Based Hybrid Dipeptide Catalysts Improves Activity and Stereoselectivity
Borges-González, Jorge,García-Monzón, Irma,Martín, Tomás
, p. 2141 - 2147 (2019)
Herein, we introduce and demonstrate how carbohydrates can be used as conformational control units of organocatalysts to tune their catalytic properties. New hybrid dipeptide-like organocatalysts based on ζ-sugar aminoacids and proline were prepared and t
Translating the Enantioselective Michael Reaction to a Continuous Flow Paradigm with an Immobilized, Fluorinated Organocatalyst
Sagamanova, Irina,Rodríguez-Escrich, Carles,Molnár, István Gábor,Sayalero, Sonia,Gilmour, Ryan,Pericàs, Miquel A.
, p. 6241 - 6248 (2015/11/23)
A novel polymer-supported fluorinated organocatalyst has been prepared and benchmarked in the enantioselective Michael addition of aldehydes to nitroalkenes. The system has proven to be highly efficient and displays excellent selectivities (er and dr) wit
Self-assembly of an organocatalyst for the enantioselective synthesis of Michael adducts and α-aminoxy alcohols in a nonpolar medium
Basceken, Sinan
, p. 1218 - 1224 (2013/10/22)
A proline-thiourea host-guest complex is described as a self-assembled organocatalyst for the enantioselective Michael addition of aldehydes to nitroolefins and for the asymmetric α-aminoxylation of both aldehydes and ketones. The Michael adducts were obt