1196147-60-0 Usage
Uses
Used in Research Applications:
Dichlorobis[3-(di-t-butylphosphino)propylamine]ruthenium(II), min. 97% is used as a catalyst for precise control of various organic reactions, such as hydrogenation, dehydrogenation, and olefin metathesis. Its high purity ensures reliable and consistent results in research settings.
Used in Industrial Applications:
In the industry, Dichlorobis[3-(di-t-butylphosphino)propylamine]ruthenium(II), min. 97% is utilized as a catalyst to facilitate efficient and controlled organic reactions. Its high purity and stability make it suitable for large-scale processes where maintaining reaction integrity is crucial.
Used in Inert Atmosphere Handling:
Dichlorobis[3-(di-t-butylphosphino)propylamine]ruthenium(II), min. 97% is typically handled and stored under an inert atmosphere to prevent degradation and ensure its stability, making it essential for maintaining the compound's reactivity and performance in various applications.
Check Digit Verification of cas no
The CAS Registry Mumber 1196147-60-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,9,6,1,4 and 7 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1196147-60:
(9*1)+(8*1)+(7*9)+(6*6)+(5*1)+(4*4)+(3*7)+(2*6)+(1*0)=170
170 % 10 = 0
So 1196147-60-0 is a valid CAS Registry Number.
1196147-60-0Relevant academic research and scientific papers
Aminophosphine ligands R2P(CH2)nNH 2 and ruthenium hydrogenation catalysts RuCl2(R 2P(CH2)nNH2)2
Jia, Wenli,Chen, Xuanhua,Guo, Rongwei,Sui-Seng, Christine,Amoroso, Dino,Lough, Alan J.,Abdur-Rashid, Kamaluddin
, p. 8301 - 8307 (2010/03/04)
The aminophosphine ligands R2P(CH2) 2NH2 and R2P(CH2)3NH 2 (R = Ph, iPr, tBu) were isolated in good to excellent yields from the reaction of LiPR2 with Cl(CH 2)2N(TMS)2 and Cl(CH2) 3N(TMS)2, respectively, followed by hydrolysis. This approach allows fine tuning of the ligands' stereoelectronic properties through the variation of the substituents on the phosphine. The aminophosphine ligands were used to prepare the ruthenium complexes RuCl2(R 2P(CH2)2NH2)2 and RuCl2(R2P(CH2)3NH2) 2 by reacting a 2:1 mixture of the respective ligand and [RuCl 2(cod)]n in an appropriate solvent. The resulting complexes were found to be excellent catalysts for the hydrogenation of ketones and imines. The Royal Society of Chemistry 2009.
