1196147-69-9 Usage
Uses
Used in Organic Synthesis:
3-(Di-i-propylphosphino)propylamine, min. 97% (10 wt% in THF) is used as a phosphine ligand for enhancing the efficiency and selectivity of catalytic reactions in organic synthesis. Its steric properties allow for better control over reaction pathways and improved yields of desired products.
Used in Coordination Chemistry:
In coordination chemistry, 3-(Di-i-propylphosphino)propylamine, min. 97% (10 wt% in THF) is used as a ligand for the coordination with transition metals. This coordination can lead to the formation of stable complexes with unique properties, which are useful in various applications such as catalysis, sensing, and materials science.
Used in Pharmaceutical Industry:
3-(Di-i-propylphosphino)propylamine, min. 97% (10 wt% in THF) is used as a building block or intermediate in the synthesis of pharmaceutical compounds. Its ability to form stable complexes with metal ions can be exploited in the development of new drugs with improved pharmacological properties.
Used in Materials Science:
3-(Di-i-propylphosphino)propylamine, min. 97% (10 wt% in THF) is used in the development of new materials with specific properties, such as catalysts, sensors, and functional coatings. Its coordination chemistry properties allow for the design of materials with tailored characteristics for various applications.
Check Digit Verification of cas no
The CAS Registry Mumber 1196147-69-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,9,6,1,4 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1196147-69:
(9*1)+(8*1)+(7*9)+(6*6)+(5*1)+(4*4)+(3*7)+(2*6)+(1*9)=179
179 % 10 = 9
So 1196147-69-9 is a valid CAS Registry Number.
1196147-69-9Relevant academic research and scientific papers
Chu, Wan-Yi,Gilbert-Wilson, Ryan,Rauchfuss, Thomas B.,Van Gastel, Maurice,Neese, Frank
, p. 2900 - 2914 (2016)
A family of CoCl2(PNpy) complexes were prepared, where PNpy = 2-iminopyridyl-phosphine ligands derived from aminoalkyl and aminoaryl phosphines and 2-keto- and 2-formylpyridines. Reduction of CoCl2(PNpy) complexes in the presence of
Aminophosphine ligands R2P(CH2)nNH 2 and ruthenium hydrogenation catalysts RuCl2(R 2P(CH2)nNH2)2
Jia, Wenli,Chen, Xuanhua,Guo, Rongwei,Sui-Seng, Christine,Amoroso, Dino,Lough, Alan J.,Abdur-Rashid, Kamaluddin
experimental part, p. 8301 - 8307 (2010/03/04)
The aminophosphine ligands R2P(CH2) 2NH2 and R2P(CH2)3NH 2 (R = Ph, iPr, tBu) were isolated in good to excellent yields from the reaction of LiPR2 with Cl(CH 2)2N(TMS)2 and Cl(CH2) 3N(TMS)2, respectively, followed by hydrolysis. This approach allows fine tuning of the ligands' stereoelectronic properties through the variation of the substituents on the phosphine. The aminophosphine ligands were used to prepare the ruthenium complexes RuCl2(R 2P(CH2)2NH2)2 and RuCl2(R2P(CH2)3NH2) 2 by reacting a 2:1 mixture of the respective ligand and [RuCl 2(cod)]n in an appropriate solvent. The resulting complexes were found to be excellent catalysts for the hydrogenation of ketones and imines. The Royal Society of Chemistry 2009.
