119640-09-4Relevant academic research and scientific papers
Synthesis of Perhydro-1,3-diazine-2-thiones from β-Chloro Imines
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas,Declercq, Jean-Paul
, p. 2587 - 2590 (2007/10/02)
The reaction of β-chloro imines with methanol gave rise to β-alkylamino acetals via intermediate 2-methoxyazetidines.If an aromatic β-chloro imine was used under these conditions, 1-methoxy-2-methyl-1-phenyl-1-propene was also formed.The reaction of β-chloro imines with potassium thiocyanate in methanol gave rise to perhydro-1,3-diazine-2-thiones in 10-55percent yield in addition to β-alkylamino acetals, again via methoxyazetidines.
A NEW METHOD FOR THE PREPARATION OF β-(ALKYLAMINO)-CARBONYL COMPOUNDS BY REARRANGEMENT OF β-CHLOROIMINES VIA AZETIDINE INTERMEDIATES
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas
, p. 2937 - 2956 (2007/10/02)
The reaction of β-chloroimines with sodium methoxide in methanol gave rise to β-(alkylamino)- and β-(arylamino)-carbonyl compounds in high yield.The reaction mechanism for the generation of β-(alkylamino)- and β-(arylamino)-carbonyl compounds passes via a
