1196434-30-6

Basic information

• Product Name: (4'-{[4-(methylthio)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate
• Synonyms: (4'-{[4-(methylthio)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate
• CAS NO: 1196434-30-6
• Molecular Weight: 661.155
• Mol File: 1196434-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4'-{[4-(methylthio)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: (4'-{[4-(methylthio)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate(1196434-30-6)
• EPA Substance Registry System: (4'-{[4-(methylthio)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate(1196434-30-6)

Safety Data

• Hazardous Substances Data: 1196434-30-6(Hazardous Substances Data)

Upstream product

• 20582-85-8 4-(methylthio)-1-butanol 

Downstream Products

• 1196434-35-1 (4'-{[4-(methylsulfinyl)butoxy]carbonyl}-1,1'-biphenyl-4-yl)(triphenyl)phosphonium perchlorate 

Relevant articles and documents

Tetraarylphosphonium salts as soluble supports for oxidative catalysts and reagents

(Figure Presented) Tetraarylphosphonium (TAP)-supported DMSO, TEMPO, and DIB reagents were synthesized and used for the oxidation of alcohols, including Swern oxidation and for the R-acetoxylation of ketones. By taking advantage of the predictable solubility properties of the TAP unit, simple precipitation and filtration of the phosphonium moiety permit complete separation of the desired oxidation products. This paper describes the preparation of these three TAP-supported oxidative reagents and their activity in the aforementioned oxidative transformations. Furthermore, we have demonstrated that these reagents can be recycled directly when used in catalytic processes and following regeneration when used in stoichiometric processes. 2009 American Chemical Society.