119649-85-3Relevant academic research and scientific papers
MILD PROTECTION AND DEPROTECTION OF ALCOHOLS AS TER-BUTYL ETHERS IN THE FIELD OF PHEROMONE SYNTHESIS
Alexakis, A.,Gardette, M.,Colin, S.
, p. 2951 - 2954 (1988)
α,ο-Halohydrins and ο-acetylenic alcohols are protected as t-butyl ethers by reaction with isobutene and an acid catalyst : Amberlyst H-15. t-Butyl ethers are, in turn, cleaved to acetates by Ac2O and 10 percent FeCl3 in Et2O solvent.Under these mild conditions conjugated dieneic systems are neither destroyed nor isomerized.
A new method for synthesis of functionalized organozinc-copper(I) reagents and their 1,4-addition reaction with enones
Hu, Yulai,Yu, Jianhua,Yang, Shiyan,Wang, Jin-Xian,Yin, Yuanqi
, p. 2793 - 2800 (1998)
The transmetalation of functionalized organozinc iodides with Cu(OAc)2 in THF provides a new convenient method for the preparation of functionalized organozinc-copper(I) reagents FG-RCu(OAc)ZnI which ultimately undergo 1,4- addition reaction wi
Nickel (II) catalysed 1,4- addition reactions of functionalised organozinc reagents with enones
Yang, Danfeng Huang Yihua,Wang, Jin-Xian,Hu, Yulai
, p. 79 - 81 (2007/10/03)
An efficient catalytic 1,4 addition reaction of functionalised organozinc reagents with enones has been developed using a nickel complex as catalyst.
