119654-85-2

Upstream product

• 13991-08-7 o-phenylenebis(diphenylphosphine) 
• 38720-22-8 (2-methyl-4-phenyl-1-oxabuta-1,3-diene)tricarbonyliron⁽⁰⁾ 

Downstream Products

• 137038-97-2 {Fe(CO)3((C₆H₅)2PC₆H₄P(C₆H₅)2)H}⁽¹⁺⁾*CF₃SO₃^(1-)={Fe(CO)3((C₆H₅)2PC₆H₄P(C₆H₅)2)H}CF₃SO₃ 

Relevant academic research and scientific papers

Calorimetric studies of the heats of protonation of the metal in Fe(CO)3(bidentate phosphine, arsine) complexes: Effects of chelate ligands on metal basicity

Titration calorimetry has been used to determine the beats of protonation (ΔHHM) of Fe(CO)3(LL) complexes (LL = dppm, dppe, dppp, dppb, dppbz, cis-dppv, arphos, dmpm, dcpe, and diars) with CF3SO3H in 1,2-dichlor

Sensitized photoreduction of cobalt(II) and iron(II). Structural characterization of 2)2PF6

Triplet-state ketones readily sensitized the photoreduction of bis(acetylacetonato)cobalt(II) or Cosolv2+ under atmospheric pressure of carbon monoxide to give Co(CO)4-.The low-valent cobalt could be trapped and isolated as phosphine-substituted metal carbonyl complexes.The crystal structure of one of the products, 2)2>PF6 has been determined.It is orthorhombic, space group Pbca, Z=8, with unit cell dimensions a 19.704(5), b 24.850(13), c 21.865(9) Angstroem.Phosphine-substituted iron(0) carbonyl complexes have also been isolated from similar photoreductions of iron(II) species.

REDUCTIVE CARBONYLATION OF IRON(II) WITH MANGANESE METAL. PREPARATION OF CARBONYL DIPHOSPINE COMPLEXES OF IRON(0)

A slective one-step method is reported for the synthesis of Fe(CO)3(P-P) derivatives (P-P = chelating tertiary diphosphine), starting from FeCl2, diphosphine and manganese, in tetrahydrofuran, under a CO atmosphere, at room temperature.The use of manganese metal as reducing agent is essential for the selectivity of the process.In the absence of the reducing agent, complexes of the type Fe(CO)2(P-P)Cl2 have been obtained.All these iron compounds have been characterized by IR and 31P NMR spectroscopy.