1197215-35-2

Upstream product

• 39482-40-1 3,3-dimethylhex-5-en-1-al 
• 100-58-3 phenylmagnesium bromide 
• 107-86-8 3,3-dimethyl acrylaldehyde 
• 95465-44-4 3-methyl-1-phenylbut-2-en-1-ol 
• 5650-07-7 3-methyl-1-phenyl-but-2-en-1-one 
• 1610543-01-5 3,3-dimethyl-1-phenylhex-5-en-1-one 

Downstream Products

• 1197215-36-3 C₂₀H₃₄OSi 

Relevant academic research and scientific papers

Enantiospecific intramolecular heck reactions of secondary benzylic ethers

Enantioenriched methylenecyclopentanes are synthesized by stereospecific, nickel-catalyzed Heck cyclizations of secondary benzylic ethers. The reaction proceeds in high yield and enantiospecificity for benzylic ethers of both π-extended and simple arenes. Ethers with pendant 1,2-disubstituted olefins form trisubstituted olefins with control of both absolute configuration and alkene geometry. Diastereoselective synthesis of a polycyclic furan is demonstrated.