119729-85-0Relevant articles and documents
Chemoselective and Stereospecific Conjugate Alkenyl Group Transfer to α-Nitroolefins using Diisobutylalkenylalanes
Pecunioso, Angelo,Menicagli, Rita
, p. 5411 - 5416 (1987)
Diisobutylalkenylalanes, easily prepared by hydroalumination of terminal, α-branched and internal alkynes, react with α-nitroolefins to give pure E-γ-nitroolefins in almost quantitative yields.The reaction described is a convenient and simple approach to E-β,γ-unsaturated carbonyl compounds.