119752-19-1Relevant academic research and scientific papers
Visible-Light-Mediated Regioselective Allylation, Benzylation, and Silylation of Methylene-Malononitriles via Photoredox-Induced Radical Cation Fragmentation
Liu, Rongfang,Chia, Shane Pui Mun,Goh, Yi Yiing,Cheo, Han Wen,Fan, Binbin,Li, Ruifeng,Zhou, Rong,Wu, Jie
, p. 1459 - 1465 (2020)
Visible-light-mediated regioselective allylation, benzylation, and silylation of methylene-malononitriles using allylic/benzylic silane and disilane reagents have been developed, delivering the corresponding allylated, benzylated, and silylated products i
Dual Regioselectivity in the Photoallylation of Electron-Deficient Alkenes by Allylic Silanes
Mizuno, Kazuhiko,Ikeda, Munehiro,Otsuji, Yoshio
, p. 1507 - 1510 (2007/10/02)
The photoreaction of 1-aryl-2,2-dicyanoethenes with allylic silanes in the presence of phenanthrene gave 4-aryl-5,5-dicyano-1-pentenes in high yields.In this photoreaction, the allylic groups were introduced regioselectively at the β-position to cyano gro
