119778-63-1

Upstream product

• 91259-92-6 (1S,2R)-6-(tert-butoxycarbonyl)-3-cyclohexene-1-carboxylic acid 
• 74-88-4 methyl iodide 
• 4841-84-3 dimethyl cis-1,2,3,6-tetrahydrophthalate 
• 31139-02-3 (1R,6S)-6-methoxycarbonyl-3-cyclohexene-1-carboxylic acid 

Downstream Products

• 863640-40-8 (1R,6R)-6-Formyl-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863639-87-6 (1R,6S)-6-Formyl-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863640-41-9 (1R,6S)-1-Methyl-6-(2-oxo-ethyl)-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863640-42-0 (1R,6S)-6-((E)-2-Methoxy-vinyl)-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863639-98-9 (1R,6S)-6-Hydroxymethyl-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863639-94-5 (1R,6S)-6-[(S)-2-Hydroxy-2-(6-oxo-cyclohex-1-enyl)-ethyl]-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863639-89-8 (1R,6S)-6-[(R)-2-Hydroxy-2-(6-oxo-cyclohex-1-enyl)-ethyl]-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 863639-95-6 (1R,6S)-6-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-2-(6-oxo-cyclohex-1-enyl)-ethyl]-1-methyl-cyclohex-3-enecarbaldehyde 
• 868944-58-5 6-[2-(tert-butyl-dimethyl-silanyloxy)-2-(6-oxo-cyclohex-1-enyl)-ethyl]-1-methyl-cyclohex-3-enecarboxylic acid tert-butyl ester 

Relevant academic research and scientific papers

EFFICIENT STEREOCONTROL OF A QUATERNARY CHIRAL CENTER IN THE CYCLOHEXENE SYSTEMS. POTENTIAL CHIRAL SYNTHONS FOR VITAMIN D AND RELATED COMPOUNDS BY ENZYMATIC APPROACH

Cyclohexene derivatives, 8-11, fused to γ-lactone with angular methyl are efficiently prepared in an enantio-, stereo- and regioselective manner from the chiral monoester 1.