1198335-17-9Relevant academic research and scientific papers
Aza-Reformatsky reaction promoted by catalytic samarium diiodide: Synthesis of β-amino esters or amides
Rodríguez-Solla, Humberto,Díaz-Pardo, Ainhoa,Concellón, Carmen,Del Amo, Vicente
, p. 1709 - 1712 (2014)
The synthesis of β-amino esters or amides has been achieved from moderate to high yields from the reaction of imines and α-halo esters or amides promoted by catalytic amounts of samarium diiodide in the presence of magnesium turnings as co-reductant. A me
The use of samarium enolates, A novel alternative in the addition reactions to imines. Synthesis of 3-amino esters, amides and enantiopure 3,4-diamino esters
Concellon, Jose M.,Rodriguez-Solla, Humberto,Simal, Carmen
experimental part, p. 1238 - 1242 (2009/12/08)
An efficient reaction of tosylimines with a range of samarium enolates (derived from esters, and amides) is reported. The reaction with the α-dibenzylamino-N-tert-butanesulfinimine derived from chiral phenylalaninal afforded the corresponding enantiopure
The addition reaction of samarium enolates and 2-haloenolates derived from esters, and amides to imines. totally stereoselective synthesis of enantiopure 3,4-diamino esters or amides
Concellon, Jose M.,Rodriguez-Solla, Humberto,Simal, Carmen,Amo, Vicente Del,Garcia-Granda, Santiago,Rosario Diaz
experimental part, p. 2991 - 3000 (2010/03/25)
The addition reaction of samarium enolates and 2-haloenolates derived from esters and amides to imines takes place in an efficient manner. A novel protocol to perform the addition reaction of samarium enolates derived from esters or amides to chiral 2-ami
