1198587-77-7Relevant academic research and scientific papers
Generation of quaternary centers by reductive cross-coupling: Shifting of regioselectivity in a subset of allylic alcohol-based coupling reactions
Yang, Dexi,Belardi, Justin K.,Micalizio, Glenn C.
scheme or table, p. 2144 - 2147 (2011/05/05)
Regioselective titanium alkoxide-mediated reductive cross-coupling reactions of allylic alcohols with vinylsilanes and imines have previously been demonstrated to proceed with allylic transposition by formal metallo-[3,3]-rearrangement [thought to proceed
A convergent stereoselective synthesis of quinolizidines and indolizidines: Chemoselective coupling of 2-hydroxymethyl-substituted allylic silanes with imines
Yang, Dexi,Micalizio, Glenn C.
supporting information; experimental part, p. 17548 - 17549 (2010/04/02)
(Chemical Equation Presented) A convergent synthesis of stereodefined indolizidines and quinolizidines through chemoselective allyl transfer between 2-hydroxymethyl-substituted allylic silanes and imines is described. Overall, highly substituted heterocyc
