1198746-20-1Relevant articles and documents
Highly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex
Zhao, Jun-Feng,Tjan, Teguh-Budiono W.,Tan, Boon-Hong,Loh, Teck-Peng
, p. 5714 - 5716 (2009)
[Chemical Equation Presented] A chiral indium(III)-pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoal
Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex
Zhao, Jun Feng,Tan, Boon Hong,Zhu, Ming Kui,Tjan, Teguh Budiono W.,Loh, Teck Peng
supporting information; experimental part, p. 2085 - 2088 (2010/10/20)
A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselecti