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1198798-61-6

[nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1198798-61-6 Structure

  • Basic information

    1. Product Name: [nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)]
    2. Synonyms:
    3. CAS NO:1198798-61-6
    4. Molecular Formula:
    5. Molecular Weight: 517.421
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1198798-61-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)](1198798-61-6)
    11. EPA Substance Registry System: [nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)](1198798-61-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1198798-61-6(Hazardous Substances Data)

1198798-61-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1198798-61-6 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,9,8,7,9 and 8 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1198798-61:
(9*1)+(8*1)+(7*9)+(6*8)+(5*7)+(4*9)+(3*8)+(2*6)+(1*1)=236
236 % 10 = 6
So 1198798-61-6 is a valid CAS Registry Number.

1198798-61-6Relevant articles and documents

Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl)2-(2,6-diisopropylphenyl) diazabutadiene

Kraikivskii,Saraev,Bocharova,Romanenko,Matveev,Petrovskii,Kuzakov

, p. 416 - 425 (2012)

A reaction of Ni(Allyl)2 with bis(2,6-diisopropylphenyl) diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction. Pleiades Publishing, Ltd., 2012.

Conversion of imine ligands in allyl-nickel(II) complexes

Kraikivskii, Peter B.,Klein, Hans-Friedrich,Saraev, Vitaly V.,Meusinger, Reinhard,Svoboda, Ingrid,Pashchanka, Mikhail

, p. 3912 - 3917 (2010/03/01)

Interaction of Ni(allyl)2 and bidentate nitrogen-containing ligands (phenanthroline-1,10; bis(2,6-diisopropylphenyl)diazabutadiene) has been studied. It has been shown that coordination of diimine ligands proceeds with transfer of an allylnickel group to the diimine frame and formation of a covalent Ni-N bond giving rise to imine(amide)Ni(II) complexes. In the case of phenanthroline dearomatization of one heteroaromatic ring takes place. The low-spin imine(amide)allyl complexes (allyl)Ni(C15H15N2) (1) and (allyl)Ni(C29H42N2) (3) have been isolated as crystals and characterized by solution spectroscopy. Combining two molar equivalents of phenanthroline-1,10 with Ni(allyl)2 results in the transfer of both allyl groups and formation of the high-spin imine(amide)Ni(II) complex Ni(C15H15N2)2 (2).

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