119884-41-2Relevant academic research and scientific papers
NEIGHBORING GROUP PARTICIPATION IN THE ACETOLYSIS OF 1,1,1-TRIARYL-3-DIAZO-2-PROPANONES. AN UNPRECEDENTED 1,3 SHIFT OF AN ARYL GROUP VIA A FIVE-MEMBERED TRANSITION STATE
Rosnati, Vittorio,Vona, M. Luisa Di,Pusino, Alba,Saba, Antonio
, p. 4193 - 4196 (1988)
The acetolysis of diazo ketones 1a,b,c, leads to the corresponding indanones 3a,b,c, and to the rearranged acetates 4a,b,c.The formation of the acetates 4 can be explained in terms of a mechanism involving the same transition state responsible for the ring closure to 3.
