119910-98-4Relevant academic research and scientific papers
vic-difluorination of fluoroalkenes with xenon difiuoride: The effect of fluorine substituents on the reaction of alkenes with xenon difluoride
Tamura, Masanori,Quan, Heng-Dao,Sekiya, Akira
, p. 3151 - 3153 (2007/10/03)
vic-Difluorination proceeds by the reaction of fluoroalkenes with xenon difluoride to afford the corresponding fluorinated compounds. From the reaction with polyfluoroalkenes, the products are obtained in high to excellent yields. In this reaction, the fluorine atom substituent of alkene stabilizes the cation intermediate and suppresses side-reactions such as rearrangement.
STEREOCHEMICAL INVESTIGATIONS. XL. CONFORMATIONAL CHARACTERISTICS OF 2-SUBSTITUTED 1,1-DIFLUOROCYCLOHEXANES. DISAPPEARANCE OF THE GAUCHE EFFECT
Zefirov, N. S.,Samoshin, V. V.,Mursakulov, I. G.,Pashinnik, V. E.,Povolotskii, M. I.,et al.
, p. 1286 - 1298 (2007/10/02)
The conformational equilibria in the series of 2-substituted 1,1-difluorocyclohexanes were investigated by comparison of the integral intensities of the signals of the conformers in the low-temperature 19F NMR and PMR spectra and from the averaged width o
