119930-53-9Relevant academic research and scientific papers
ETUDE DE QUELQUES REACTIONS DE LA TRIS(TERT-BUTYL)PHENYLPHOSPHINE
Navech, J.,Germa, H.,Mathieu, S.
, p. 247 - 260 (2007/10/02)
The reaction of tris(tert-butyl)phenylphosphine with some hydrogen acceptors has been investigated.Triphenylcarbenium hexafluorophosphate allows to obtain a phosphonium salt: the possibility of preliminary formation of phosphenium with a P-H bond during this reaction is discussed.With methyltrifluoromethanesulfonate, two pentacoordinated phosphorus compounds are isolated.Diethylazodicarboxylate gives rise to a ?3,λ5-phosphorane.The transient formation of phosphinidene and of 1,2-bis(ethylcarboxylate) 3-tris(tert-butyl)phenyldiazaphosphirine is discussed.
ETUDE DE L'ACTION DE L'AZODICARBOXYLATE DE DIETHYLE SUR LA TRIS(TERT-BUTYL)PHENYLPHOSPHINE
Navech, J.,Revel, M.
, p. 2863 - 2866 (2007/10/02)
The reaction of diethylazodicarboxylate with tris(tert-butyl)phenylphosphine gives rise to a ?3, λ5- phosphorane.Evidence is given for the transient formation of a diazaphosphiridine derivative.
