119930-83-5Relevant academic research and scientific papers
Iron-mediated synthesis of t-butyl-N-(aryloxy)carbamates
Holden,Cole
, p. 2579 - 2586 (2007/10/02)
The anion of t-butyl-N-hydroxycarbamate displaces halogens from (η6-haloarene)(η5-cyclopentadienyliron) salts. The resulting complexes are demetallated by photolysis in sunlight to generate t-butyl-N-(aryloxy)carbamates.
Nucleophilic Aromatic Substitution on Tricarbonyl(halogenoarene)chromium Complexes: A New Synthesis of O-Arylhydroxylamines
Baldoli, Clara,Buttero, Paola Del,Licandro, Emanuela,Maiorana, Stefano
, p. 344 - 345 (2007/10/02)
A series of O-arylhydroxylamines 4 have been synthesized under mild conditions and in good yields by the reaction of tricarbonyl(halogenoarene)chromium complexes 1 with N-(tert-butyloxycarbonyl)hydroxylamine (tert-butyl N-hydroxycarbamate), followed by decomplexation and acidic hydrolysis of the tert-butyl N-(aryloxy)carbamates 3.
