119951-85-8

Basic information

• Product Name: 1-hydroperoxy-1,2-dihydroacenaphthylene
• Synonyms: 1-hydroperoxy-1,2-dihydroacenaphthylene
• CAS NO: 119951-85-8
• Molecular Weight: 186.21
• Mol File: 119951-85-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-hydroperoxy-1,2-dihydroacenaphthylene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-hydroperoxy-1,2-dihydroacenaphthylene(119951-85-8)
• EPA Substance Registry System: 1-hydroperoxy-1,2-dihydroacenaphthylene(119951-85-8)

Safety Data

• Hazardous Substances Data: 119951-85-8(Hazardous Substances Data)

Upstream product

• 83-32-9 acenaphthene 

Downstream Products

• 2235-15-6 1(2H)-acenaphthylenone 

Relevant articles and documents

Kinetic studies of acenaphthene oxidation catalyzed by N-Hydroxyphthalimide

The acenaphthene oxidation with molecular oxygen in the presence of N-hydroxyphthalimide (NHPI) has been investigated. It is shown that the main oxidation product is acenaphthene hydroperoxide. The phthalimide-N-oxyl (PINO) radical has been generated in situ from its hydroxyimide parent, NHPI, by oxidation with iodobenzenediacetate. The rate constant of H-abstraction (k H) from acenaphthene by PINO has been determined spectroscopically in acetonitrile. The kinetic isotope effect and the activation parameters have also been measured. On the basis of the results of our studies and available published literature data, a plausible mechanism for the oxidation process of acenaphthene with dioxygen catalyzed by NHPI was discussed.

Oxidation of cumene and acenaphthene by oxygen in the presence of tetraalkylammonium perchlorates

Tetraalkylammonium perchlorates catalyze oxidation of cumene and acenaphthene by oxygen. The perchlorates are more stable in these reactions than halides with the same cations. The perchlorate-initiated decomposition of hydroperoxides depends on the structure of the latter: secondary acenaphthyl hydroperoxide reacts with perchlorates more readily than does tertiary cumyl hydroperoxide. 1996 MAEe Cyrillic signΚ Hayκa/Interperiodica Publishing.